惰性键和惰性分子的活化重组
C1化学:CO2为碳源的绿色有机合成
碳氢键活化重组
2006.06-2009.05 美国威斯康星大学-麦迪逊分校,药学院,博士 (导师:Richard Hsung)
2005.09-2006.06 美国明尼苏达大学-双城分校,化学系,研究生学习(导师:Richard Hsung)
2001.09-2005.06 中国科学技术大学,化学系,学士 (导师:尤田耙)
2021.04至今 上海交通大学变革性分子前沿科学中心,研究员
2013.12-2021.03 中科院福建物质结构研究所,研究员
2010.07-2013.12 斯克里普斯研究所,化学系,博士后/研究助理(导师:Jin-Quan Yu)
2009.05-2010.07 埃默里大学,化学系,博士后 (导师:Albert Padwa)
入选福建省百人计划;获得国家自然科学基金委优秀青年科学基金项目、福建省杰出青年科学基金项目资助;获得Thieme Chemistry Journals Award 国际学术奖。研究成果发表在Nature、Nature Catalysis,Nature Communications、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Chemical Science等核心杂志。部分研究成果被国际著名杂志Nature、Nature Catalysis,Angew. Chem. Int. Ed.和 Chemical & Engineering News (C&EN) 等做为研究亮点报道。实现了研究成果的商品化,获得了研究的相关专利。受邀为Jacs、Angew,Acs Catalysis,Chemical Science等国际核心化学相关杂志的审稿人。
"Ligand-enabled site-selectivity in a versatile rhodium(II)-catalysed aryl C–H carboxylation with CO2." Fu, L.;† Li, S.;† Cai, Z.; Ding, Y.; Guo, X.-Q.; Zhou, L.-P.; Yuan, D.; Sun, Q.-F.; Li, G.* Nature Catalysis 2018, 1, 469. (*通讯作者)
"Palladium-Catalyzed Enantioselective Isodesmic C–H Iodination of Phenylacetic Weinreb Amides." Wang, H.; Zhou, C.; Gao, Z.; Li, S.; Li, G.* Angew. Chem. Int. Ed. 2023, e202300905. DOI: 10.1002/anie.202300905
"Visible-light-driven Reductive Carboarylation of Styrenes with CO2 and Aryl Halides." Wang, H.; Gao, Y.; Zhou, C.; Li, G.* J. Am. Chem. Soc. 2020, 142, 8122.
"Spirocyclizative Remote Arylcarboxylation of Nonactivated Arenes with CO2 via Visible-Light-Induced Reductive Dearomatization." Gao, Y.; Wang, H.; Chi, Z.; Yang, L.; Zhou, C.; Li, G.* CCS Chem. 2022, 4, 1565.
"Carboxyl as a Remote-selective Chelating Group for C–H Activation of Arenes." Li, S.;† Wang, H.; † Weng, Y.; Li, G.* Angew. Chem. Int. Ed. 2019, 58, 18502.
"Arene C-H Iodination using Aryl Iodides." Li, S.;† Zhang, C.;† Fu, L.; Wang, H.; Cai, L.; Chen, X.; Wang, X.; Li, G.* CCS Chem. 2022, 4, 1889. (†equal contribution)
"Asymmetric Remote meta-C−H Activation Controlled by a Chiral Ligand." Wang, H.; Li, H.; Chen, X.; Zhou, C.; Li, S.; Yang, Y.-F.* Li, G.* ACS Catal. 2022, 12, 13435.
"Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives." Li, S.;† Cai, L.;† Ji, H.; Yang, L.; Li, G.* Nature Commun. 2016, 7, 10443.
"Pd(II)-catalyzed meta-C–H bromination and chlorination of aniline and benzoic acid derivatives." Wang, H.; Fu, L.; Zhou, C.; Li, G.* Chem. Sci. 2022, 13, 8686.
"Palladium-catalyzed remote para-C–H activation of arenes assisted by a recyclable pyridine-based template." Li, S.; Wang, H.; Weng, Y.; Li, G.* Chem. Sci. 2021, 12, 4126.
"Pd(II)-catalyzed remote regiodivergent ortho- and meta-C–H functionalizations of phenylethylamines." Li, S.;† Ji, H.;† Cai, L.; Li, G.* Chem. Sci. 2015, 6, 5595.
"Rhodium(ii)-catalyzed C–H carboxylation of ferrocenes with CO2." Lv, H.; Wang, X.; Hao, Y.; Ma, C.; Li, S.*; Li, G.*; Zhang, J. Green Chem. 2023, 25, 554.
"Visible-Light-Driven Regioselective Carbocarboxylation of 1,3-Dienes with Organic Halides and CO2" Zhou, C.; Wang, X.; Yang, L.; Fu, L.;* Li, G.* Green Chem. 2022, 24, 6100.
"Rh(I)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2." Cai, L.; Fu, L.; Zhou, C.; Gao, Y.; Li, S.; Li, G.* Green Chem. 2020, 22, 7328.
"Rhodium(I)-Catalyzed Aryl C-H Carboxylation of 2-Arylanilines with CO2." Gao, Y.; Cai, Z.; Li, S.; Li, G.* Org. Lett. 2019, 21, 3663.
"Pd(II)-Catalyzed C–H Functionalizations Directed by Distal Weakly Coordinating Functional Groups." Li, G.; Wan, L.; Zhang, G.; Leow, D.; Spangler, J.; Yu, J.-Q.* J. Am. Chem. Soc. 2015, 137, 4391.
"Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups." Zhang, M.; Zhang, Y.; Jie, X.; Zhao, H.; Li, G.;* Su, W.* Org. Chem. Front. 2014, 1, 843.
"Conformation-Induced Remote meta-C–H Activation of Amines." Tang, R.-Y.; Li, G.; Yu, J.-Q.* Nature 2014, 507, 215.
"Activation of Remote meta-C–H Bonds Assisted by an End-on Template." Leow, D.;† Li, G.;† Mei, T.-S.; Yu, J.-Q.* Nature 2012, 486, 518. (†equal contribution)
"Ether-Directed ortho-C–H Olefination with a Palladium(II)/Monoprotected Amino Acid Catalyst." Li, G.; Leow, D.; Wan, L.; Yu, J.-Q* Angew. Chem. Int. Ed. 2012, 52, 1245.