课题组长

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李纲

职位:研究员

电子邮箱:gang.li@sjtu.edu.cn

办公地点:

个人网页/课题组主页地址:https://orcid.org/0000-0001-5229-554X

研究方向:

  • 惰性键和惰性分子的活化重组

  • C1化学:CO2为碳源的绿色有机合成

  • 碳氢键活化重组

教育背景:

  • 2006.06-2009.05  美国威斯康星大学-麦迪逊分校,药学院,博士

  • 2005.09-2006.06  美国明尼苏达大学-双城分校,化学系,研究生学习

  • 2001.09-2005.06  中国科学技术大学,化学系,学士

工作经历:

  • 2021.04至今   上海交通大学变革性分子前沿科学中心,研究员

  • 2013.12-2021.03  中科院福建物质结构研究所,研究员

  • 2010.07-2013.12  斯克里普斯研究所,化学系,博士后/研究助理

  • 2009.05-2010.07  埃默里大学,化学系,博士后

学术任职、荣誉与获奖:

    入选福建省百人计划;获得国家自然科学基金委优秀青年科学基金项目、福建省杰出青年科学基金项目资助;获得Thieme Chemistry Journals Award 国际学术奖。研究成果发表在Nature、Nature Catalysis,Nature Communications、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Chemical Science等核心杂志。部分研究成果被国际著名杂志Nature、Nature Catalysis,Angew. Chem. Int. Ed.和 Chemical & Engineering News (C&EN) 等做为研究亮点报道。实现了研究成果的商品化,获得了研究的相关专利。受邀为Jacs、Angew,Acs Catalysis,Chemical Science等国际核心化学相关杂志的审稿人。

学术成果:

  • "Ligand-enabled site-selectivity in a versatile rhodium(II)-catalysed aryl C–H carboxylation with CO2." Fu, L.;† Li, S.;† Cai, Z.; Ding, Y.; Guo, X.-Q.; Zhou, L.-P.; Yuan, D.; Sun, Q.-F.; Li, G.* Nature Catalysis 2018, 1, 469.

  • "Spirocyclizative Remote Arylcarboxylation of Nonactivated Arenes with CO2 via Visible-Light-Induced Reductive Dearomatization." Gao, Y.; Wang, H.; Chi, Z.; Yang, L.; Zhou, C.; Li, G.* CCS Chem. 2021, 3, 1848.

  • "Arene C-H Iodination using Aryl Iodides." Li, S.;† Zhang, C.;† Fu, L.; Wang, H.; Cai, L.; Chen, X.; Wang, X.; Li, G.* CCS Chem. 2021, DOI: 10.31635/ccschem.021.202101156.

  • "Visible-light-driven Reductive Carboarylation of Styrenes with CO2 and Aryl Halides." Wang, H.; Gao, Y.; Zhou, C.; Li, G.* J. Am. Chem. Soc. 2020, 142, 8122.

  • "Rh(I)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2." Cai, L.; Fu, L.; Zhou, C.; Gao, Y.; Li, S.; Li, G.* Green Chem. 2020, 22, 7328.

  • "Rhodium(I)-Catalyzed Aryl C-H Carboxylation of 2-Arylanilines with CO2." Gao, Y.; Cai, Z.; Li, S.; Li, G.* Org. Lett. 2019, 21, 3663.

  • "Carboxyl as a Remote-selective Chelating Group for C–H Activation of Arenes." Li, S.;† Wang, H.; † Weng, Y.; Li, G.* Angew. Chem. Int. Ed. 2019, 58, 18502.

  • "Palladium-catalyzed remote para-C–H activation of arenes assisted by a recyclable pyridine-based template." Li, S.; Wang, H.; Weng, Y.; Li, G.* Chem. Sci. 2021, 12, 4126.

  • "Ligand Promoted, Palladium-Catalyzed C(sp2)–H Arylation of Free Primary 2-Phenylethylamines." Ding, Y.; Fan, S.; Chen, X.; Gao, Y.* Li, S.; Li, G.* Org. Lett. 2019, 21, 4224.

  • "Rhodium(II)-Catalyzed Aryl C–H Carboxylation of 2-Pyridylphenols with CO2." Cai, Z.; Li, S.; Gao, Y.; Li, G.* Adv. Synth. Catal. 2018. 360, 4005.

  • "Palladium-Catalyzed Direct C–H Carbonylation of Free Primary Benzylamines: A Synthesis of Benzolactams." Zhang, C.; Ding, Y.; Gao, Y.; Li, S.;* Li, G.* Org. Lett. 2018, 20, 2095.

  • "Weak, Bidentate Chelating Group Assiste Cross-Coupling of C(sp3)–H Bonds in Aliphatic Acid Derivatives with Aryltrifluoroborates." Cai, Z.; Li, S.; Gao, Y.; Fu, L.; Li, G.* Chem. Commun. 2018, 54, 12766.

  • "Palladium-Catalyzed C–H Trifluoroethoxylation of N-Sulfonylbenzamides." Yang, L.; Li, S.; Cai, L.; Ding, Y.; Fu, L.; Cai, Z.; Ji, H.;* Li, G.* Org. Lett. 2017, 19, 2746.

  • "Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives." Li, S.;† Cai, L.;† Ji, H.; Yang, L.; Li, G.* Nature Commun. 2016, 7, 10443.

  • "Pd(II)-catalyzed remote regiodivergent ortho- and meta-C–H functionalizations of phenylethylamines." Li, S.;† Ji, H.;† Cai, L.; Li, G.* Chem. Sci. 2015, 6, 5595.

  • "Pd(II)-Catalyzed C–H Functionalizations Directed by Distal Weakly Coordinating Functional Groups." Li, G.; Wan, L.; Zhang, G.; Leow, D.; Spangler, J.; Yu, J.-Q.* J. Am. Chem. Soc. 2015, 137, 4391.

  • "Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups." Zhang, M.; Zhang, Y.; Jie, X.; Zhao, H.; Li, G.;* Su, W.* Org. Chem. Front. 2014, 1, 843.

  • "Conformation-Induced Remote meta-C–H Activation of Amines." Tang, R.-Y.; Li, G.; Yu, J.-Q.* Nature 2014, 507, 215.

  • "Activation of Remote meta-C–H Bonds Assisted by an End-on Template." Leow, D.;† Li, G.;† Mei, T.-S.; Yu, J.-Q.* Nature 2012, 486, 518.

  • "Ether-Directed ortho-C–H Olefination with a Palladium(II)/Monoprotected Amino Acid Catalyst." Li, G.; Leow, D.; Wan, L.; Yu, J.-Q* Angew. Chem. Int. Ed. 2012, 52, 1245.